Bis(5-amino-4-aminocarbonyl-1H-imidazol-3-ium) (5-amino-4-aminocarbonyl-1H-imidazol-3-ium-κO)-di-μ-chlorido-heptachlorido-dibismuth(III) monohydrate
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منابع مشابه
Bis(5-amino-4-aminocarbonyl-1H-imidazol-3-ium) (5-amino-4-aminocarbonyl-1H-imidazol-3-ium-κO)-di-μ-chlorido-heptachlorido-dibismuth(III) monohydrate
The title compound, (C(4)H(7)N(4)O)(2)[Bi(2)Cl(9)(C(4)H(7)N(4)O)]·H(2)O, was prepared by the reaction of bis-muth trichloride and 5-amino-1H-imidazole-4-carboxamide in a dilute HCl medium. The asymmetric unit contains two 5-amino-4-amino-carbonyl-1H-imidazol-3-ium cations, one edge-shared non-centrosymmetric biocta-hedral [Bi(2)C1(9)(C(4)H(7)N(4)O)](2-) dianion and a water mol-ecule. In the dia...
متن کامل1H-Imidazol-3-ium-4-carboxylate
In the title compound, C(4)H(4)N(2)O(2), both imidazole N atoms are protonated and carboxyl-ate group is deprotonated, resulting in a zwitterion. The mol-ecule is essentially planar, with an r.m.s. deviation of 0.012 (1) Å. In the crystal, N-H⋯O hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.674 (2) Å] between the imidazole rings link the mol-ecules into a three-d...
متن کاملPoly[1H-imidazol-3-ium [di-μ-nitrato-sodium]]
In the title compound {(C3H5N2)[Na(NO3)2]} n , the Na(I) ion is coordinated by eight O atoms from three bidentate nitrate anions and two O atoms from two monodentate nitrate anions, displaying a bicapped trigonal-prismatic geometry. The imidazolium cation is essentially planar (r.m.s. deviation for all non-H atoms = 0.0018 Å). In the crystal, the Na(I) ions are connected by bridging nitrate lig...
متن کاملBis{3-amino-1-carbamothioyl-5-[(2-{[(5-methyl-1H-imidazol-3-ium-4-yl)methyl]sulfanyl}ethyl)amino]-1H-1,2,4-triazol-4-ium} hexachloridobismuthate(III) nitrate dihydrate
The asymmetric unit of the title hydrated salt, (C10H18N8S2)2[BiCl6]NO3·2H2O, contains two independent 3-amino-1-carbamo-thioyl-5-[(2-{[(5-methyl-1H-imidazol-3-ium-4-yl)meth-yl]sulfan-yl}eth-yl)amino]-1H-1,2,4-triazol-4-ium cations, one hexa-chloridobismuthate anion, one nitrate anion and two solvent water mol-ecules. The dihedral angles between the imidazole and triazole rings in the cations a...
متن کامل1-(4-Carboxyphenyl)-1H-imidazol-3-ium chloride dihydrate
In the crystal structure of the title compound, C(10)H(9)N(2)O(2) (+)·Cl(-)·2H(2)O, the components are linked by O-H⋯O, N-H⋯O, O-H⋯Cl and N-H⋯Cl hydrogen bonds. In the cation, the imidazole ring is oriented at a dihedral angle of 13.67 (17)° with respect to the benzene ring. In the crystal, π-π stacking occurs between nearly parallel benzene rings, which are oriented at a dihedral angle of 3.4 ...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808009367